from an article by Matthew Holohan
TCP/IP stands for Transmission Control Protocol/Internet Protocol. Although these words may be daunting, TCP/IP is nothing more than a language that computers use to communicate with each other over the Internet. The TCP/IP system functions in two layers: TCP and IP. To get an idea of how this works, review the following description of a typical TCP/IP transfer.
To access the Internet, your computer needs to understand TCP/IP. If you have Windows 95 or later, or Mac OS 7.5 or later, TCP/IP is included in your system software.
When you set up your computer to use the Internet, you might use a TCP/IP control panel or control panel section. Your ISP will need to tell you what settings to use in these control panels; the settings vary greatly from ISP to ISP. (Some ISPs will make the settings for you automatically if you use your modem to set up your account.)
TCP/IP wasn't created to work over serial lines, such as your telephone line. PPP, or the Point-to-Point protocol, is one way of translating TCP/IP over a modem connection. Typically, your computer will connect to your ISP via PPP, and then connect from your ISP's computers via TCP/IP. The above description is very general. To fully understand the finer points of TCP/IP, further research is suggested.
Try : Microsoft TechNet - Introduction to TCP/IP in Windows NT 4.0